The game turned on 53 minutes when City goalkeeper Claudio Bravo was sent off on his return to the Nou Camp for deliberate handball. Barca ruthlessly made their numerical advantage count as Messi struck twice in eight minutes to notch his 37th club treble.
Jeremy Mathieu's dismissal for two bookable offences failed to derail the hosts as Neymar, having missed an 87th-minute penalty, atoned with Barca's fourth a minute from time. Victory moves Barca five points clear of second-placed City - who went a fourth game without a win in all competitions - in Group C with three games to play.
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